Issue 32, 2014

Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3

Abstract

Two alkyl and aryl substituted five-membered zirconacycloallenoids underwent a typical σ-alkyl metallocene reaction with B(C6F5)3, namely cleavage of the Zr–C(sp3) bond with formation of zwitterionic (η2-allenyl)zirconium/alkylborate products. Both products were characterized by X-ray crystal structural analyses.

Graphical abstract: Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3

Supplementary files

Article information

Article type
Paper
Submitted
17 Apr 2014
Accepted
20 Jun 2014
First published
23 Jun 2014

Dalton Trans., 2014,43, 12210-12213

Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3

G. Bender, C. G. Daniliuc, B. Wibbeling, G. Kehr and G. Erker, Dalton Trans., 2014, 43, 12210 DOI: 10.1039/C4DT01137F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements