Issue 9, 2014
From the journal:

New Journal of Chemistry

Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes†

Nan Cao,a   Teng Liu,a   Jun Su,b   Xiaojun Wu,a   Wei Luo*ac  and  Gongzhen Chenga  

* Corresponding authors

a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, P. R. China
E-mail: wluo@whu.edu.cn
Tel: +86 2768752366

b Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, Hubei, P. R. China

c Suzhou Institute of Wuhan University, Suzhou, Jiangsu, P. R. China

Abstract

Ultrafine Ru nanoparticles were successfully immobilized inside the pores of MIL-101 by using a simple liquid impregnation method. The turnover frequency (TOF) value of the as-synthesized 2.80 wt% Ru@MIL-101 toward catalytic hydrolysis of ammonia borane is 178 mol H2 minβˆ’1 (mol Ru)βˆ’1, which is among the highest values ever reported.

Graphical abstract: Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes

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Article information

DOI
https://doi.org/10.1039/C4NJ00739E
Article type
Letter
Submitted
07 May 2014
Accepted
24 Jun 2014
First published
25 Jun 2014

New J. Chem., 2014,38, 4032-4035

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Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes

N. Cao, T. Liu, J. Su, X. Wu, W. Luo and G. Cheng, New J. Chem., 2014, 38, 4032 DOI: 10.1039/C4NJ00739E

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