Issue 6, 2014
From the journal:

Organic Chemistry Frontiers

Polythiophene synthesis via halogen dance†‡

Keisuke Shono,a   Yugo Sumino,a   Shota Tanaka,a   Shunsuke Tambaa  and  Atsunori Mori*a  

* Corresponding authors

a Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501, Japan
E-mail: amori@kobe-u.ac.jp

Abstract

Polymerization of 2,4-dibromo-3-hexyl-5-lithiated thiophene that is formed by deprotonation of 2,5-dibromo-3-hexylthiophene with LDA and following halogen dance takes place in the presence of a nickel(II) or palladium(II) catalyst to afford poly(3-bromo-4-hexylthiophen-2,5-diyl).

Graphical abstract: Polythiophene synthesis via halogen dance

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Article information

DOI
https://doi.org/10.1039/C4QO00109E
Article type
Research Article
Submitted
08 Apr 2014
Accepted
16 May 2014
First published
16 May 2014

Org. Chem. Front., 2014,1, 678-682

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Polythiophene synthesis via halogen dance

K. Shono, Y. Sumino, S. Tanaka, S. Tamba and A. Mori, Org. Chem. Front., 2014, 1, 678 DOI: 10.1039/C4QO00109E

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