Issue 9, 2016
From the journal:

Chemical Society Reviews

New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

Christos E. Kefalidis,a   Ludovic Castro,a   Lionel Perrin,b   Iker Del Rosala  and  Laurent Maron*a  

* Corresponding authors

a LPCNO, UMR 5215, Université de Toulouse-CNRS, INSA, UPS, 135 Avenue de Rangueil, 31077 Toulouse, France
E-mail: Laurent.maron@irsamc.ups-tlse.fr

b Univ Lyon, Université Lyon1, CNRS, INSA, CPE-Lyon, ICBMS, UMR 5246, 43, Bd du 11 novembre 1918, 69622 Villeurbanne cedex, France

Abstract

A fifteen year contribution of computational studies carried out in close synergy with experiments is summarized. This interplay has allowed some important breakthroughs in the field of organolanthanide chemistry. The variety of different reaction mechanisms in lanthanide chemistry appear to be broader than the simple bond metathesis.

Graphical abstract: New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

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Article information

DOI
https://doi.org/10.1039/C5CS00907C
Article type
Review Article
Submitted
05 Jan 2016
First published
09 Mar 2016

Chem. Soc. Rev., 2016,45, 2516-2543

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New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

C. E. Kefalidis, L. Castro, L. Perrin, I. D. Rosal and L. Maron, Chem. Soc. Rev., 2016, 45, 2516 DOI: 10.1039/C5CS00907C

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