Issue 20, 2021
From the journal:

Chemical Communications

Isolable small-molecule cysteine sulfenic acid†

Tsukasa Sano,a   Ryosuke Masuda,a   Shohei Sasea  and  Kei Goto ORCID logo *a  

* Corresponding authors

a Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Japan
E-mail: goto@chem.titech.ac.jp

Abstract

An isolable small-molecule cysteine sulfenic acid (Cys–SOH) protected by a molecular cradle was synthesized by direct oxidation of the corresponding cysteine thiol and its structure was established by X-ray crystallographic analysis. Studies on biologically relevant reactivity indicated its usefulness as a biorepresentative small-molecule sulfenic acid model.

Graphical abstract: Isolable small-molecule cysteine sulfenic acid

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Article information

DOI
https://doi.org/10.1039/D0CC08422K
Article type
Communication
Submitted
04 Jan 2021
Accepted
15 Feb 2021
First published
15 Feb 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 2479-2482

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Isolable small-molecule cysteine sulfenic acid

T. Sano, R. Masuda, S. Sase and K. Goto, Chem. Commun., 2021, 57, 2479 DOI: 10.1039/D0CC08422K

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