Issue 31, 2007
From the journal:

Dalton Transactions

Self-assembled hetero-bimetallic coordination cage and cation-clusters with µ2-Cl bridging using a flexible two-arm ferrocene amide linker†‡

Kai-Ju Wei,a   Jia Ni,b   Yong-Shu Xie,a   Yangzhong Liu*a  and  Qing-Liang Liu*a  

* Corresponding authors

a Department of Chemistry, University of Science and Technology of China, Hefei, China
E-mail: liuyz@ustc.edu.cn and qliu@ustc.edu.cn
Fax: +86 551 3603388
Tel: +86 551 3600874

b Center Lab, Shantou University, Shantou, China

Abstract

One flexible, discrete coordination cage [Cu2(3-BPFA)4(H2O)2](ClO4)4·4CH3OH (1), and two cation-clusters with µ2-Cl bridging [Ni2(µ-Cl)(3-BPFA)4(H2O)2](ClO4)3 (2) and [Co2(µ-Cl)(3-BPFA)4(H2O)2](ClO4)4·4CH3OH (3), containing the ferrocenyl functionality were prepared via coordination-driven self-assembly and Cl-anion template from CuII, NiII and CoII salts and a flexible two-arm molecule 1,1-bis[(3-pyridylamino)carbonyl]ferrocene (3-BPFA).

Graphical abstract: Self-assembled hetero-bimetallic coordination cage and cation-clusters with µ2-Cl bridging using a flexible two-arm ferrocene amide linker

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B703363J
Article type
Paper
Submitted
06 Mar 2007
Accepted
06 Jun 2007
First published
28 Jun 2007

Dalton Trans., 2007, 3390-3397

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Self-assembled hetero-bimetallic coordination cage and cation-clusters with µ2-Cl bridging using a flexible two-arm ferrocene amide linker

K. Wei, J. Ni, Y. Xie, Y. Liu and Q. Liu, Dalton Trans., 2007, 3390 DOI: 10.1039/B703363J

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