Issue 5, 2008
From the journal:

Dalton Transactions

Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and ironvs.palladium complexes: unprecedented N,N-coordination for a N,P,N ligand†‡§

Anthony Kermagoreta  and  Pierre Braunstein*a  

* Corresponding authors

a Laboratoire de chimie de coordination, Institut de Chimie (UMR 7177 CNRS), Université Louis Pasteur, 4 rue Blaise Pascal, Strasbourg, France
E-mail: braunstein@chimie.u-strasbg.fr
Fax: +33 390 241 322

Abstract

Unexpected N,N-coordination of the potentially tridentate N,P,N-ligand bis(2-oxazolin-2,5,5-trimethyl)phenylphosphine occurs in Co(II) and Fe(II) complexes, in contrast to the P,N- or N,P,N-coordination modes observed in Pd(II) complexes; this leads to the formation of unprecedented eight-membered ring chelates.

Graphical abstract: Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and ironvs.palladium complexes: unprecedented N,N-coordination for a N,P,N ligand

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Article information

DOI
https://doi.org/10.1039/B717021C
Article type
Communication
Submitted
31 Aug 2007
Accepted
05 Nov 2007
First published
16 Nov 2007

Dalton Trans., 2008, 585-587

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Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and ironvs.palladium complexes: unprecedented N,N-coordination for a N,P,N ligand

A. Kermagoret and P. Braunstein, Dalton Trans., 2008, 585 DOI: 10.1039/B717021C

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