Issue 10, 2009
From the journal:

CrystEngComm

Orientation of Mn12 molecular nanomagnets in self-assembled monolayers

Benoit Fleury,a   Vincent Huc,*a   Laure Catala,a   Pascale Jegou,b   Laurent Baraton,b   Christophe David,c   Serge Palacinb  and  Talal Mallah*a  

* Corresponding authors

a Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS, Université Paris-Sud 11, Orsay, France
E-mail: mallah@icmo.u-psud.fr, vincenthuc@icmo.u-psud.fr
Fax: (+33) (0)1 69 15 47 54
Tel: (+33) (0)1 69 15 47 49

b Laboratoire de Chimie des Surfaces et Interfaces, SCPCI, DRECAM, DSM, CEA Saclay, Gif sur Yvette, France

c Laboratoire de Photonique et de Nanostructures, CNRS, route de Nozay, Marcoussis, France

Abstract

The oriented grafting of the Mn12-carboxylate molecular nanomagnets has been achieved on semi-conducting flat Si(100) functionalized surfaces due to the bonding selectivity between axial and equatorial carboxylate groups present in the coordination sphere of the Mn12 complexes.

Graphical abstract: Orientation of Mn12 molecular nanomagnets in self-assembled monolayers

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Article information

DOI
https://doi.org/10.1039/B908525D
Article type
Paper
Submitted
29 Apr 2009
Accepted
24 Jul 2009
First published
24 Aug 2009

CrystEngComm, 2009,11, 2192-2197

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Orientation of Mn12 molecular nanomagnets in self-assembled monolayers

B. Fleury, V. Huc, L. Catala, P. Jegou, L. Baraton, C. David, S. Palacin and T. Mallah, CrystEngComm, 2009, 11, 2192 DOI: 10.1039/B908525D

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