Issue 1, 2011

A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

Abstract

A new D2A-type charge-transfer three-dimensional network with a charge distribution of [{Ru2}δ+–(BTDA-TCNQ2δ)–{Ru2}δ+] where δ ≈ 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(II, II) complex ([Ru2]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).

Graphical abstract: A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2010
Accepted
14 Jul 2010
First published
17 Aug 2010

Chem. Commun., 2011,47, 271-273

A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

H. Miyasaka, T. Morita and M. Yamashita, Chem. Commun., 2011, 47, 271 DOI: 10.1039/C0CC02031A

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