Issue 45, 2011

Synthesis of two-dimensional phenylene–boroxine networks through in vacuo condensation and on-surface radical addition

Abstract

We report on covalent two-dimensional phenyleneboroxine hybrid-networks that were synthesized under ultra-high vacuum conditions from doubly functionalized monomers through thermally activated condensation prior to deposition and successive heterogeneously catalyzed radical addition on Ag(111). Structural properties were characterized in situ by high resolution Scanning-Tunneling-Microscopy (STM).

Graphical abstract: Synthesis of two-dimensional phenylene–boroxine networks through in vacuo condensation and on-surface radical addition

Supplementary files

Article information

Article type
Communication
Submitted
30 Jun 2011
Accepted
10 Oct 2011
First published
19 Oct 2011

Chem. Commun., 2011,47, 12355-12357

Synthesis of two-dimensional phenyleneboroxine networks through in vacuo condensation and on-surface radical addition

S. Schlögl, T. Sirtl, J. Eichhorn, W. M. Heckl and M. Lackinger, Chem. Commun., 2011, 47, 12355 DOI: 10.1039/C1CC13896K

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