Issue 43, 2011
From the journal:

Chemical Communications

Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes†

Samir Barman,a   Hiroyasu Furukawa,*b   Olivier Blacque,a   Koushik Venkatesan,a   Omar M. Yaghi,b   Guo-Xin Jinc  and  Heinz Berke*a  

* Corresponding authors

a Department of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland
E-mail: berke@aci.uzh.ch
Fax: +41 44-635-6802

b Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California-Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, USA
E-mail: furukawa@chem.ucla.edu

c Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, P. R. China

Abstract

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal–linker complex as a precursor to construct MOF-648.

Graphical abstract: Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes

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Article information

DOI
https://doi.org/10.1039/C1CC14387E
Article type
Communication
Submitted
20 Jul 2011
Accepted
27 Sep 2011
First published
10 Oct 2011

Chem. Commun., 2011,47, 11882-11884

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Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes

S. Barman, H. Furukawa, O. Blacque, K. Venkatesan, O. M. Yaghi, G. Jin and H. Berke, Chem. Commun., 2011, 47, 11882 DOI: 10.1039/C1CC14387E

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