Chiral crystalline solids of ammonium-templated ErIII–formate frameworks assembled from three achiral acentric components

Bin Liu; Hai-Bin Zheng; Zhe-Ming Wang; Song Gao

doi:10.1039/C1CE05250K

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Chiral crystalline solids of ammonium-templated Er^III–formate frameworks assembled from three achiral acentric components†

Bin Liu,^a Hai-Bin Zheng,^a Zhe-Ming Wang*^a and Song Gao*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: zmw@pku.edu.cn, gaosong@pku.edu.cn
Fax: +86-10-62751708

Abstract

The assembly of three simple achiral but acentric building blocks, protonated monoamine AH⁺, formate HCOO⁻ and Er³⁺, resulted in a series of chiral crystals of ammonium-templated erbium–formate frameworks with formula [AH⁺][Er(HCOO)₄⁻], indicating that the increased opportunity to obtain chiral crystalline solids could be achieved by incorporating multiple acentric centers within the lattice.

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Article information

DOI: https://doi.org/10.1039/C1CE05250K
Article type: Communication
Submitted: 24 Feb 2011
Accepted: 10 Jun 2011
First published: 12 Jul 2011

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CrystEngComm, 2011,13, 5285-5288

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Chiral crystalline solids of ammonium-templated Er^III–formate frameworks assembled from three achiral acentric components

B. Liu, H. Zheng, Z. Wang and S. Gao, CrystEngComm, 2011, 13, 5285 DOI: 10.1039/C1CE05250K

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