Synthesis, characterization and application of carbon nanocages as anode materials for high-performance lithium-ion batteries

Abstract

Carbon nanocages (CNCs) with diameters of about 200∼500 nm have been synthesized by a simple method. The electrochemical properties of the CNCs as anode materials were evaluated by discharge/charge measurement and electrochemical impedance spectroscopy. Results showed that the CNCs displayed excellent cycling performance and good rate capability with no noticeable capacity fading up to 50 cycles at current densities of 100, 300 and 500 mA g⁻¹. Their electrochemical properties were significantly improved after annealing treatment of the CNCs at 600 °C. For example, the CNCs(2)-annealed exhibited much better electrochemical performance with a high reversible capacity of 520 mAh g⁻¹ after 50 cycles at current density of 100 mA g⁻¹. A discharge capacity of 380 mAh g⁻¹ can be obtained after 50 cycles at high current density of 500 mA g⁻¹. The results of the Raman, thermal gravimetric and electrochemical impedance analysis indicated that the graphitization degree, electronic conductivity and charge-transfer rate of the CNCs have been improved after annealing treatment.