Issue 20, 2012

Mechanochemical reactions of coordination polymers by grinding with KBr

Abstract

Grinding of a one-dimensional (1-D) ladder coordination polymer (CP), [Zn(μ-CH3CO2)(CF3CO2)bpe] (1), and a hydrogen-bonded 1-D CP, [Cd(CH3CO2)2bpe(H2O)] (2), with KBr resulted in the exchange of carboxylate by bromide ions and the formation of 1-D zigzag and 2-D CPs respectively.

Graphical abstract: Mechanochemical reactions of coordination polymers by grinding with KBr

Supplementary files

Article information

Article type
Communication
Submitted
25 Nov 2011
Accepted
10 Jan 2012
First published
01 Feb 2012

Chem. Commun., 2012,48, 2585-2587

Mechanochemical reactions of coordination polymers by grinding with KBr

M. Nagarathinam, A. Chanthapally, S. H. Lapidus, P. W. Stephens and J. J. Vittal, Chem. Commun., 2012, 48, 2585 DOI: 10.1039/C2CC17358A

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