Issue 50, 2012
From the journal:

Chemical Communications

Silver(i)-catalyzed carboxylation of arylboronic esters with CO2†

Xiao Zhang,a   Wen-Zhen Zhang,*a   Ling-Long Shi,a   Chun-Xiao Guo,a   Ling-Ling Zhanga  and  Xiao-Bing Lu*a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, P. R. China
E-mail: zhangwz@dlut.edu.cn, lxb-1999@163.com
Fax: +86 411 8498 6256
Tel: +86 411 8498 6257

Abstract

A variety of arylboronic esters were efficiently carboxylated with CO2 using a simple AgOAc/PPh3 catalyst, affording the corresponding carboxylic acids in good yield. This simple and efficient silver(I) catalytic system showed wide functional group compatibility.

Graphical abstract: Silver(i)-catalyzed carboxylation of arylboronic esters with CO2

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Article information

DOI
https://doi.org/10.1039/C2CC32045B
Article type
Communication
Submitted
21 Mar 2012
Accepted
08 May 2012
First published
10 May 2012

Chem. Commun., 2012,48, 6292-6294

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Silver(I)-catalyzed carboxylation of arylboronic esters with CO2

X. Zhang, W. Zhang, L. Shi, C. Guo, L. Zhang and X. Lu, Chem. Commun., 2012, 48, 6292 DOI: 10.1039/C2CC32045B

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