Issue 39, 2013

Oxo-sulfido- and oxo-selenido-molybdenum(vi) complexes possessing a dithioleneligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

Abstract

Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.

Graphical abstract: Oxo-sulfido- and oxo-selenido-molybdenum(vi) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

Supplementary files

Article information

Article type
Communication
Submitted
24 Jul 2012
Accepted
08 Oct 2012
First published
08 Oct 2012

Chem. Commun., 2013,49, 4358-4360

Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

H. Sugimoto, S. Tatemoto, K. Toyota, K. Ashikari, M. Kubo, T. Ogura and S. Itoh, Chem. Commun., 2013, 49, 4358 DOI: 10.1039/C2CC35345H

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