A novel benzene–water azeotrope route to new Na-based metal fluorosulphates NaFeSO4F and NaFeSO4F·2H2O in one minute

Zhengqiu Yuan; Denghu Wei; Yan Wang; Yongchun Zhu; Yitai Qian; Kaibing Tang

doi:10.1039/C2CE25155H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A novel benzene–water azeotrope route to new Na-based metal fluorosulphates NaFeSO₄F and NaFeSO₄F·2H₂O in one minute†

Zhengqiu Yuan,^a Denghu Wei,^a Yan Wang,^a Yongchun Zhu,*^a Yitai Qian*^a and Kaibing Tang^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: yuanzhengqiu@163.com
Fax: + 86-551-3607402
Tel: + 86-551-3601589

Abstract

A one-step benzene–water azeotrope method has been carried out for the first time for the selective preparation of NaFeSO₄F and NaFeSO₄F·2H₂O starting from FeSO₄·7H₂O and NaF in a short time (1 min) at a low temperature (200 °C) in an autoclave with different sealed caps using benzene as a reaction medium and dehydrant.

Download options Please wait...

Supplementary files

Supplementary information PDF (414K)

Article information

DOI: https://doi.org/10.1039/C2CE25155H
Article type: Communication
Submitted: 03 Feb 2012
Accepted: 02 Mar 2012
First published: 02 Mar 2012

Download Citation

CrystEngComm, 2012,14, 4251-4254

Permissions

Request permissions

A novel benzene–water azeotrope route to new Na-based metal fluorosulphates NaFeSO₄F and NaFeSO₄F·2H₂O in one minute

Z. Yuan, D. Wei, Y. Wang, Y. Zhu, Y. Qian and K. Tang, CrystEngComm, 2012, 14, 4251 DOI: 10.1039/C2CE25155H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm