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The incorporation of (2S)-[methyl-–13C]methionine and [1,2-13C2]acetate into fusarin A, a metabolite of Fusarium moniliforme, points to a biosynthetic pathway involving the condensation of a C14-polyketide and a C4 intermediate, e.g. oxaloacetate, of the Krebs tricarboxylic acid cycle.
P. S. Steyn and R. Vleggaar, J. Chem. Soc., Chem. Commun., 1985, 1189 DOI: 10.1039/C39850001189
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