Issue 45, 2013

A highly porous agw-type metal–organic framework and its CO2 and H2adsorption capacity

Abstract

An unsymmetrical tricarboxylate ligand with linking alkyne moiety has been used to construct a highly porous metal–organic framework with agw topology. The obtained Cu(II) MOF exhibits a high BET surface area of 3337.0 m2 g−1, a large capacity of CO2 (21.2 mmol g−1 at 298 K and 20 bar) and a good H2 adsorption (5.8 wt% at 77 K and 20 bar).

Graphical abstract: A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

Supplementary files

Article information

Article type
Communication
Submitted
12 Jun 2013
Accepted
14 Aug 2013
First published
15 Aug 2013

CrystEngComm, 2013,15, 9348-9351

A highly porous agw-type metal–organic framework and its CO2 and H2 adsorption capacity

Z. Lu, L. Du, B. Zheng, J. Bai, M. Zhang and R. Yun, CrystEngComm, 2013, 15, 9348 DOI: 10.1039/C3CE41119B

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