Issue 12, 2013
From the journal:

RSC Advances

Solvent-free arylamination catalysed by [Pd(NHC)] complexes†

Anthony Chartoire,a   Arnaud Boreux,a   Anthony R. Martina  and  Steven P. Nolan*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK
E-mail: snolan@st-andrews.ac.uk.
Fax: (+44) 1334 463 808
Tel: (+44) 1334 463 763

Abstract

A highly effective solvent-free protocol for the Buchwald–Hartwig amination of unactivated aryl chlorides is described. The effect of various [Pd(NHC)] pre-catalyst systems on the reactivity has been studied. [Pd(IPr*)(cin)Cl] is reported as the complex of choice for the transformation.

Graphical abstract: Solvent-free aryl amination catalysed by [Pd(NHC)] complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3RA40386F
Article type
Communication
Submitted
23 Jan 2013
Accepted
24 Jan 2013
First published
13 Feb 2013

RSC Adv., 2013,3, 3840-3843

Permissions

Request permissions

Solvent-free aryl amination catalysed by [Pd(NHC)] complexes

A. Chartoire, A. Boreux, A. R. Martin and S. P. Nolan, RSC Adv., 2013, 3, 3840 DOI: 10.1039/C3RA40386F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements