Synthesis and characterization of N-2-aryl-1,2,3-triazole based iridium complexes as photocatalysts with tunable photoredox potential

Rong Cai; Wuming Yan; Matthew G. Bologna; Kaushalya de Silva; Zhao Ma; Harry O. Finklea; Jeffrey L. Petersen; Minyong Li; Xiaodong Shi

doi:10.1039/C4QO00281D

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Synthesis and characterization of N-2-aryl-1,2,3-triazole based iridium complexes as photocatalysts with tunable photoredox potential†

Rong Cai,^a Wuming Yan,^a Matthew G. Bologna,^a Kaushalya de Silva,^a Zhao Ma,^b Harry O. Finklea,^a Jeffrey L. Petersen,^a Minyong Li

*^b and Xiaodong Shi*^a

Author affiliations

* Corresponding authors

^a C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, WV 26506, USA
E-mail: Xiaodong.Shi@mail.wvu.edu
Fax: +1-304-293-4904
Tel: +1-304-293-0179

^b Department of Medicinal Chemistry, School of Pharmacy, Shandong University, Jinan, Shandong, China
E-mail: mli@sdu.edu.cn
Fax: +86-531-8838-2076

Abstract

N-2-Aryl chelated 1,2,3-triazole-Ir(III) complexes with various substituents were prepared for the first time. These photoactive Ir(III) complexes were characterized by X-ray crystallography and their redox potentials were evaluated. This study revealed a new class of photocatalysts with tunable photoredox potentials.

This article is part of the themed collection: Celebrating the 80th Birthday of Professor Ei-ichi Negishi

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DOI: https://doi.org/10.1039/C4QO00281D
Article type: Research Article
Submitted: 29 Oct 2014
Accepted: 27 Dec 2014
First published: 30 Dec 2014

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Org. Chem. Front., 2015,2, 141-144

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Synthesis and characterization of N-2-aryl-1,2,3-triazole based iridium complexes as photocatalysts with tunable photoredox potential

R. Cai, W. Yan, M. G. Bologna, K. de Silva, Z. Ma, H. O. Finklea, J. L. Petersen, M. Li and X. Shi, Org. Chem. Front., 2015, 2, 141 DOI: 10.1039/C4QO00281D

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Organic Chemistry Frontiers

Synthesis and characterization of N-2-aryl-1,2,3-triazole based iridium complexes as photocatalysts with tunable photoredox potential†

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Synthesis and characterization of N-2-aryl-1,2,3-triazole based iridium complexes as photocatalysts with tunable photoredox potential

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