Two robust metal–organic frameworks with uncoordinated N atoms for CO2 adsorption

Guo-Jian Ren; Yan-Qing Liu; Tong-Liang Hu; Xian-He Bu

doi:10.1039/C5CE01340B

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Two robust metal–organic frameworks with uncoordinated N atoms for CO₂ adsorption†

Guo-Jian Ren,^a Yan-Qing Liu,^a Tong-Liang Hu*^a and Xian-He Bu^a

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* Corresponding authors

^a School of Materials Science and Engineering, National Institute for Advanced Materials, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, PR China
E-mail: tlhu@nankai.edu.cn
Fax: +86 22 23502458

Abstract

Two highly porous metal–organic frameworks are successfully constructed through the assembling of Co/Ni ions and mixed ligands. From the contribution of the uncoordinated tetrazolate N atoms of the ligand the two complexes show high CO₂ adsorption capacities, serving as potential CO₂ adsorption materials.

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Article information

DOI: https://doi.org/10.1039/C5CE01340B
Article type: Communication
Submitted: 09 Jul 2015
Accepted: 25 Sep 2015
First published: 25 Sep 2015

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CrystEngComm, 2015,17, 8198-8201

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Two robust metal–organic frameworks with uncoordinated N atoms for CO₂ adsorption

G. Ren, Y. Liu, T. Hu and X. Bu, CrystEngComm, 2015, 17, 8198 DOI: 10.1039/C5CE01340B

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