Issue 25, 2016

Highly crystalline covalent organic frameworks from flexible building blocks

Abstract

Two novel 2D covalent organic frameworks (TPT-COF-1 and TPT-COF-2) were synthesized from the flexible 2,4,6-triaryloxy-1,3,5-triazine building blocks on a gram scale, which show high crystallinity and large surface area. The controllable formation of highly ordered frameworks is mainly attributed to the self-assembly Piedfort unit of 2,4,6-triaryloxy-1,3,5-triazine.

Graphical abstract: Highly crystalline covalent organic frameworks from flexible building blocks

Supplementary files

Article information

Article type
Communication
Submitted
05 Feb 2016
Accepted
01 Mar 2016
First published
01 Mar 2016

Chem. Commun., 2016,52, 4706-4709

Highly crystalline covalent organic frameworks from flexible building blocks

L. Xu, S. Ding, J. Liu, J. Sun, W. Wang and Q. Zheng, Chem. Commun., 2016, 52, 4706 DOI: 10.1039/C6CC01171C

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