Issue 40, 2017
From the journal:

Chemical Communications

Stable (sila)difluoromethylboranes via C–F activation of fluoroform derivatives†

Shigekazu Ito, ORCID logo *a   Naoto Katoa  and  Koichi Mikami*a  

* Corresponding authors

a Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8552, Japan
E-mail: ito.s.ao@m.titech.ac.jp, mikami.k.ab@m.titech.ac.jp

Abstract

Lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-uide activates the C–F linkage of fluoroform (CF3H) and the Ruppert–Prakash reagent (CF3SiMe3) to provide difluoromethyl-substituted boranes as air-stable compounds.

Graphical abstract: Stable (sila)difluoromethylboranes via C–F activation of fluoroform derivatives

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Article information

DOI
https://doi.org/10.1039/C7CC02327H
Article type
Communication
Submitted
27 Mar 2017
Accepted
21 Apr 2017
First published
21 Apr 2017

Chem. Commun., 2017,53, 5546-5548

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Stable (sila)difluoromethylboranes via C–F activation of fluoroform derivatives

S. Ito, N. Kato and K. Mikami, Chem. Commun., 2017, 53, 5546 DOI: 10.1039/C7CC02327H

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