Issue 44, 2018
From the journal:

Chemical Communications

A robust and unique iron(ii) mosaic-like MOF†

Estefania Fernandez-Bartolome,a   José Santos, ORCID logo a   Saeed Khodabakhshi,a   Laura J. McCormick, ORCID logo b   Simon J. Teat,b   Cristina Saenz de Pipaon,c   Jose R. Galan-Mascarós, ORCID logo cd   Nazario Martín ORCID logo ae  and  Jose Sanchez Costa ORCID logo *a  

* Corresponding authors

a IMDEA Nanociencia, C/ Faraday 9, Ciudad Universitaria de Cantoblanco, Madrid, Spain
E-mail: jose.sanchezcosta@imdea.org

b Advanced Light Source, Berkeley Laboratory, 1, Cyclotron Road, Berkeley, CA 94720, USA

c Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST), Avda. Països Catalans, 16, Tarragona, Spain

d ICREA, Pg. Lluís Companys, 23, Barcelona, Spain

e Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid, Spain

Abstract

A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.

Graphical abstract: A robust and unique iron(ii) mosaic-like MOF

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Article information

DOI
https://doi.org/10.1039/C8CC01561A
Article type
Communication
Submitted
26 Feb 2018
Accepted
30 Apr 2018
First published
30 Apr 2018

Chem. Commun., 2018,54, 5526-5529

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A robust and unique iron(II) mosaic-like MOF

E. Fernandez-Bartolome, J. Santos, S. Khodabakhshi, L. J. M<small xmlns="http://www.rsc.org/schema/rscart38"> <sup>c</sup> </small>Cormick, S. J. Teat, C. S. de Pipaon, J. R. Galan-Mascarós, N. Martín and J. Sanchez Costa, Chem. Commun., 2018, 54, 5526 DOI: 10.1039/C8CC01561A

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