Issue 2, 1997
From the journal:

Chemical Communications

Stabilization of neutral oxophlorin π-radicals by bulky meso-alkyl groups

Richard G. Khoury,   Laurent Jaquinod,   Amy M. Shachter,   Nora Y. Nelson  and  Kevin M. Smith  

Abstract

The 15-tert-butyl-5-oxophlorin 1 forms a stable, neutral π-radical species 2, in high yield; the 13,17-bis-unsubstituted 5-oxophlorin analogue 5, under similar conditions, affords the 15-iso-5-oxophlorin 6 and 15-hydroxy compound 7 (both characterized by X-ray crystallography), the latter demonstrating the trapping of the π-radical by dioxygen.

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Article information

DOI
https://doi.org/10.1039/A607076K
Article type
Paper

Chem. Commun., 1997, 215-216

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Stabilization of neutral oxophlorin π-radicals by bulky meso-alkyl groups

R. G. Khoury, L. Jaquinod, A. M. Shachter, N. Y. Nelson and K. M. Smith, Chem. Commun., 1997, 215 DOI: 10.1039/A607076K

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