17O and 1H NMR chemical shifts of hydroxide and hydronium ion in aqueous solutions of strong electrolytes
Abstract
The
17
O and
1
H NMR chemical shifts of water
[δ(
17
OH
2
),
δ(
1
H
2
O)] in aqueous solutions of NaCl,
NaBr, NaI, NaNO
3
, NaClO
4
, NaOH, KCl, KBr,
KNO
3
and KOH have been measured and used to determine the
δ(
17
O), and δ(
1
H) chemical shifts of
hydroxide ion and some of its aqua-complexes. The
δ(
17
O), and δ(
1
H) chemical shifts
for the OH
-
···nH
2
O
and H
+
···nH
2
O
complexes are discussed.
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