Issue 16, 1997
From the journal:

Chemical Communications

A new manganese cluster topology capable of yielding high-spin species: mixed-valence [Mn7(OH)3Cl3(hmp)9]2 + with S ≥ 10

Milissa A. Bolcar,   Sheila M. J. Aubin,   Kirsten Folting,   David N. Hendrickson  and  George Christou  

Abstract

The reaction between MnCl 2 ·4H 2 O, Hhmp (Hhmp = 2-hydroxymethylpyridine) and NEt 4 MnO 4 in MeCN gives NEt 4 [Mn 7 (OH) 3 Cl 3 (hmp) 9 ]Cl[MnCl 4 ] 1; the 4 Mn II , 3 Mn III cation comprises a Mn 6 hexagon containing a central Mn ion, and it possesses a S ≥ 10 ground state.

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Article information

DOI
https://doi.org/10.1039/A703007J
Article type
Paper

Chem. Commun., 1997, 1485-1486

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A new manganese cluster topology capable of yielding high-spin species: mixed-valence [Mn7(OH)3Cl3(hmp)9]2 + with S ≥ 10

M. A. Bolcar, S. M. J. Aubin, K. Folting, D. N. Hendrickson and G. Christou, Chem. Commun., 1997, 1485 DOI: 10.1039/A703007J

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