Issue 20, 1997

Thioether macrocycles as spacers for crystal engineering: synthesis and crystal structures of [Ag2([24]aneS8)(CF3SO3)2(MeCN)2] and [Ag([16]aneS4)(BF4)]([24]aneS8 = 1,4,7,10,13,16,19,22-octathiacyclotetracosane; [16]aneS4 = 1,5,9,13-tetrathiacyclohexadecane)

Abstract

The polymeric complexes [Ag2([24]aneS8)(CF3SO3)2- (MeCN)2] and [Ag([16]aneS4)(BF4)] show infinite ladder and layered structures respectively, with the thioether crown controlling the multi-dimensional architecture.

Article information

Article type
Paper

Chem. Commun., 1997, 1943-1944

Thioether macrocycles as spacers for crystal engineering: synthesis and crystal structures of [Ag2([24]aneS8)(CF3SO3)2(MeCN)2] and [Ag([16]aneS4)(BF4)]([24]aneS8 = 1,4,7,10,13,16,19,22-octathiacyclotetracosane; [16]aneS4 = 1,5,9,13-tetrathiacyclohexadecane)

A. J. Blake and M. Schröder, Chem. Commun., 1997, 1943 DOI: 10.1039/A704796G

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