Issue 6, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions. Crystal structures of [AuCu(dpnapy)3][ClO4]2 and [AuCd(dpnapy)3][ClO4]3

Wing-Han Chan,   Kung-Kai Cheung,   Thomas C. W. Mak  and  Chi-Ming Che  

Abstract

Reaction of dpnapy [dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine] with [Au(tht)Cl] (tht = tetrahydrothiophene) in dichloromethane afforded [Au(dpnapy)3]+, which shows a strong affinity towards CuI and CdII ions; crystal structures of [AuCu(dpnapy)3][ClO4]2 and [AuCd(dpnapy)3][ClO4]3 revealed that [Au(dpnapy)3]+ functions as a metalloligand with the three naphthyridyl groups positioned in a trigonal fashion.

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Article information

DOI
https://doi.org/10.1039/A800061A
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 873-874

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Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions. Crystal structures of [AuCu(dpnapy)3][ClO4]2 and [AuCd(dpnapy)3][ClO4]3

W. Chan, K. Cheung, T. C. W. Mak and C. Che, J. Chem. Soc., Dalton Trans., 1998, 873 DOI: 10.1039/A800061A

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