Reactions between [M(H2O)3(tacn)]3+ (M = Cr, Co) and [Co(CN)3(tacn)] are demonstrated to produce the molecular box clusters [Cr4Co4(CN)12(tacn)8]12+ and [Co8(CN)12- (tacn)8]12+ with core structures consisting of a single cubic unit excised from the Prussian Blue type framework.
J. L. Heinrich, P. A. Berseth and J. R. Long, Chem. Commun., 1998, 1231 DOI: 10.1039/A802351D
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