Synthesis and characterization of [NBu4]4[Ag2{Mo5O13(OMe)4(NO)}2], a novel polyoxomolybdate complex with a short AgI···AgI distance
Abstract
In methanol, the defect nitrosylpolyoxomolybdate [Mo5O13(OMe)4(NO)]3– reacts with Ag+ to give the complex [Ag2{Mo5O13(OMe)4(NO)}2]4– which displays attractive interactions between the two square-planar closed-shell AgI cations.