SCHEDULED MAINTENANCE
Tri(1-naphthyl)phosphine gives palladacycles which are very active catalysts for Heck reactions; mechanisms based on a PdII–PdIV cycle are proposed and a new, very efficient method of separating the product from the catalyst has been devised, which involves treatment with cyanide ion.
B. L. Shaw, Chem. Commun., 1998, 1361 DOI: 10.1039/A802642D
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