The azuliporphyrin-carbaporphyrin connection†
Abstract
Under base catalyzed conditions, reaction of azuliporphyrin 3 with tert-butyl hydroperoxide affords the benzocarbaporphyrins 2a and 2b; a mechanism for the formation of 2b is proposed.
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Under base catalyzed conditions, reaction of azuliporphyrin 3 with tert-butyl hydroperoxide affords the benzocarbaporphyrins 2a and 2b; a mechanism for the formation of 2b is proposed.
T. D. Lash, Chem. Commun., 1998, 1683 DOI: 10.1039/A803575J
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