Issue 22, 1998

Alkanes to nitriles and α-iminoesters. Polyoxotungstate photocatalytic radical chain initiation

Abstract

Irradiation of W10O324– or PW12O403–, alkanes and methyl cyanoformate in CH3CN solution produces either the corresponding nitriles or α-iminoesters with high selectivity, depending on the temperature, via a mechanism involving two roles for the polyoxotungstate.

Article information

Article type
Paper

Chem. Commun., 1998, 2467-2468

Alkanes to nitriles and α-iminoesters. Polyoxotungstate photocatalytic radical chain initiation

Z. Zheng and C. L. Hill, Chem. Commun., 1998, 2467 DOI: 10.1039/A805036H

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