Issue 21, 1998
From the journal:

Chemical Communications

Bis{(2-diphenylphosphino)phenyl}mercury: a novel bidentate ligand and transfer reagent for the o-C6H4PPh2 group

Martin A. Bennett,   Maria Contel,   David C. R. Hockless  and  Lee L. Welling  

Abstract

The compound [Hg(o-C6H4PPh2)2] behaves as a trans-spanning bidentate ditertiary phosphine in its PdCl2 complex, the two metal atoms being forced into close contact; the palladium(0) complex [Pd{(o-Ph2PC6H4)2Hg}2] undergoes reductive elimination on heating with formation of the coupled product o-Ph2PC6H4C6H4PPh2-o.

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Article information

DOI
https://doi.org/10.1039/A806494F
Article type
Paper

Chem. Commun., 1998, 2401-2402

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Bis{(2-diphenylphosphino)phenyl}mercury: a novel bidentate ligand and transfer reagent for the o-C6H4PPh2 group

M. A. Bennett, M. Contel, D. C. R. Hockless and L. L. Welling, Chem. Commun., 1998, 2401 DOI: 10.1039/A806494F

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