Issue 23, 1998

First structural characterisation of nitro–nitrito linkage isomers of nickel(II): synthesis and single crystal structures of [NiL2(NO2)2] and [NiL2(ONO)2] [L = 1-(2-aminoethyl)piperidine]

Abstract

The linkage isomers trans-bis[1-(2-aminoethyl)piperidine]dinitronickel(II) (brown) 1 and trans-bis[1-(2-aminoethyl)piperidine]dinitritonickel(II) (blue) 2 have been synthesized and characterised by X-ray single crystal structure analysis.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 3987-3990

First structural characterisation of nitro–nitrito linkage isomers of nickel(II): synthesis and single crystal structures of [NiL2(NO2)2] and [NiL2(ONO)2] [L = 1-(2-aminoethyl)piperidine]

D. Das, I. Rahaman Laskar, A. Ghosh, A. Mondal, K. Okamoto and N. Ray Chaudhuri, J. Chem. Soc., Dalton Trans., 1998, 3987 DOI: 10.1039/A806858E

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