Issue 3, 1999

Complexation of stable carbenes with alkali metals

Abstract

Stable diaminocarbenes, including imidazol-2-ylidenes, undergo complexation with lithium, sodium and potassium species; the crystal structure of a complex of 1,3-diisopropyl-3,4,5,6-tetrahydropyrimid-2-ylidene 1 with KN(SiMe3)2 is reported.

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Article information

Article type
Paper

Chem. Commun., 1999, 241-242

Complexation of stable carbenes with alkali metals

R. W. Alder, M. E. Blake, C. Bortolotti, S. Bufali, C. P. Butts, E. Linehan, J. M. Oliva, A. Guy Orpen and M. J. Quayle, Chem. Commun., 1999, 241 DOI: 10.1039/A808951E

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