Issue 6, 1998

The structures and magnetic properties of complexes containing 3d- and 4f-metals

Abstract

Heterometallic complexes containing 3d-/4f-metals have been made with a variety of ligands including Schiff-bases, pyridonates and amino-alcohols. The majority of species with Schiff-base ligands are trinuclear with Cu2Ln cores, and with other ligands larger oligomers are found, ranging as large as Cu12La8 and Cu12Ln6 clusters (Ln = Y, Nd, Sm or Gd). The magnetic properties displayed by these polynuclear species are discussed, and the magnetic coupling between CuII and GdIII is always found to be ferromagnetic.

Article information

Article type
Paper

Chem. Soc. Rev., 1998,27, 447-452

The structures and magnetic properties of complexes containing 3d- and 4f-metals

R. E. P. Winpenny, Chem. Soc. Rev., 1998, 27, 447 DOI: 10.1039/A827447Z

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