Issue 7, 1999

Synthesis and X-ray crystal structure of [Na(18-crown-6)][U(Cp*)2(SBut)(S)], the first f-element compound containing a metal–sulfur double bond

Abstract

The C–S bond cleavage of a thiolate ligand of [U(Cp*)2(SBut)2] was induced by treatment with Na(Hg) and the title compound was isolated after addition of 18-crown-6; the crystal structure exhibited the unsupported U–S–Na linkage of the molecular complex, with a U–S bond distance of 2.462(2) Å.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 659-660

Synthesis and X-ray crystal structure of [Na(18-crown-6)][U(Cp*)2(SBut)(S)], the first f-element compound containing a metal–sulfur double bond

L. Ventelon, C. Lescop, T. Arliguie, M. Ephritikhine, P. C. Leverd, M. Lance and M. Nierlich, Chem. Commun., 1999, 659 DOI: 10.1039/A900466A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements