Issue 18, 1999
From the journal:

Chemical Communications

First example of B–C bond cleavage in the BArF (B[C6H3(CF3)2-3,5]4) anion mediated by a transition metal species, trans-[(Ph3P)2Pt(Me)(OEt2)]+

Wayde V. Konze,   Brian L. Scott  and  Gregory J. Kubas  

Abstract

The first example of transition metal-mediated decomposition of the widely used BArF anion (BArF = B[C6H3(CF3)2-3,5]4) has been accomplished by mild heating of the cationic platinum complex trans-[(Ph3P)2Pt(Me)(OEt2)]+(BArF)– in low-coordinating solvents to form the diarylated product trans-(Ph3P)2Pt(ArF)2 in good yield, thus demonstrating that such non-interacting anions can react with electrophilic transition metal complexes.

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DOI
https://doi.org/10.1039/A902274K
Article type
Paper

Chem. Commun., 1999, 1807-1808

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First example of B–C bond cleavage in the BArF (B[C6H3(CF3)2-3,5]4) anion mediated by a transition metal species, trans-[(Ph3P)2Pt(Me)(OEt2)]+

W. V. Konze, B. L. Scott and G. J. Kubas, Chem. Commun., 1999, 1807 DOI: 10.1039/A902274K

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