Issue 14, 1999

Mg0-promoted selective C–F bond cleavage of trifluoromethyl ketones: a convenient method for the synthesis of 2,2-difluoro enol silanes

Abstract

2,2-Difluoro enol silyl ethers were readily prepared by Mg0 promoted selective defluorination of trifluoromethyl ketones in the presence of TMSCl, which involves C–F bond cleavage.

Article information

Article type
Paper

Chem. Commun., 1999, 1323-1324

Mg0-promoted selective C–F bond cleavage of trifluoromethyl ketones: a convenient method for the synthesis of 2,2-difluoro enol silanes

H. Amii, T. Kobayashi, Y. Hatamoto and K. Uneyama, Chem. Commun., 1999, 1323 DOI: 10.1039/A903681D

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