Issue 17, 1999

Novel oxo-peroxo molybdenum(VI) complexes incorporating 8-quinolinol: synthesis, structure and catalytic uses in the environmentally benign and cost-effective oxidation method of methyl benzenes: Ar(CH3)n (n = 1, 2)

Abstract

A hitherto unknown distorted pentagonal bipyramidal complex, [MoO(O2)(QO)2], very efficiently catalyses homogeneous liquid phase oxidation of methylbenzenes, viz. toluene and o- and p-xylenes to benzoic acid, phthalic acid and p-toluic acid respectively, using H2O2 and O2 as oxidants.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 1627-1628

Novel oxo-peroxo molybdenum(VI) complexes incorporating 8-quinolinol: synthesis, structure and catalytic uses in the environmentally benign and cost-effective oxidation method of methyl benzenes: Ar(CH3)n (n = 1, 2)

R. Bandyopadhyay, S. Biswas, R. Bhattacharyya, S. Guha and A. K. Mukherjee, Chem. Commun., 1999, 1627 DOI: 10.1039/A904440J

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