Issue 18, 1999

(NBun4+)3[Re6S8Cl6]3–·: synthesis and luminescence of the paramagnetic, open shell member of a hexanuclear chalcohalide cluster redox system

Abstract

The chemical and electrochemical synthesis, X-ray crystal structure, magnetic characterization, absorption and luminescence spectra of (NBun4)3[Re6S8Cl6], the 23-electron cluster core member of the reversible redox couple [Re6S8Cl6]4––[Re6S8Cl6]3–· is reported.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 1867-1868

(NBun4+)3[Re6S8Cl6]3–·: synthesis and luminescence of the paramagnetic, open shell member of a hexanuclear chalcohalide cluster redox system

C. Guilbaud, A. Deluzet, B. Domercq, P. Molinié, K. Boubekeur, P. Batail and C. Coulon, Chem. Commun., 1999, 1867 DOI: 10.1039/A904669K

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