(NBun4+)3[Re6S8Cl6]3–·: synthesis and luminescence of the paramagnetic, open shell member of a hexanuclear chalcohalide cluster redox system
Abstract
The chemical and electrochemical synthesis, X-ray crystal structure, magnetic characterization, absorption and luminescence spectra of (NBun4)3[Re6S8Cl6], the 23-electron cluster core member of the reversible redox couple [Re6S8Cl6]4––[Re6S8Cl6]3–· is reported.