Issue 20, 1999

Aqueous solubilization of crystalline fullerenes by supramolecular complexation with γ-cyclodextrin and sulfocalix[8]arene under mechanochemical high-speed vibration milling

Abstract

The solid-state supramolecular complexation of fullerenes C60 and C70 as well as some derivatives of C60 was attained with γ-cyclodextrin by the use of a mechanochemical high-speed vibration milling technique. Similarly C60 and the fullerene dimer C120 were complexed with sulfocalix[8]arene. The complexes produced were found to be soluble in water, and their solubility was examined by UV-vis spectroscopy.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 2963-2966

Aqueous solubilization of crystalline fullerenes by supramolecular complexation with γ-cyclodextrin and sulfocalix[8]arene under mechanochemical high-speed vibration milling

K. Komatsu, K. Fujiwara, Y. Murata and T. Braun, J. Chem. Soc., Perkin Trans. 1, 1999, 2963 DOI: 10.1039/A904736K

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