A hexa-adduct of [60]fullerene was synthesized by addition of a mesomorphic twin cyanobiphenyl malonate derivative to C60; whereas the malonate derivative gave a monotropic nematic phase, the fullerene hexa-adduct showed an enantiotropic smectic A phase.
T. Chuard, R. Deschenaux, A. Hirsch and H. Schönberger, Chem. Commun., 1999, 2103 DOI: 10.1039/A905058B
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