Issue 18, 1999
From the journal:

Chemical Communications

Efficient transfer hydrogenation of alkynes and alkenes with methanol catalysed by hydrido(methoxo)iridium(III) complexes

Kazuhide Tani,   Aika Iseki  and  Tsuneaki Yamagata  

Abstract

Hydrido(methoxo)iridium(III) complexes, [{Ir(H)(diphosphine)}2(µ-OMe)2(µ-Cl)]+Cl– [diphosphine = (R)-BINAP 2a or = 2,2′-bis(diphenylphosphino)-1,1′-biphenyl (BPBP) 2b] catalysed transfer hydrogenation of alkynes with methanol to give trans-alkenes selectively; plausible reaction pathways are also proposed.

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Article information

DOI
https://doi.org/10.1039/A905765J
Article type
Paper

Chem. Commun., 1999, 1821-1822

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Efficient transfer hydrogenation of alkynes and alkenes with methanol catalysed by hydrido(methoxo)iridium(III) complexes

K. Tani, A. Iseki and T. Yamagata, Chem. Commun., 1999, 1821 DOI: 10.1039/A905765J

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