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The synthesis and characterisation of the first {2Fe2S}-cluster bearing both CO and CN ligands is described; the iron atoms are linked by the bridging 1,3-propanedithiolate unit that has been identified in the crystallographic structure of the {2Fe2S} sub-unit of the H-centre of the all-iron hydrogenase from Desulfovibrio desulfuricans.
A. Le Cloirec, S. C. Davies, D. J. Evans, D. L. Hughes, C. J. Pickett, S. P. Best and S. Borg, Chem. Commun., 1999, 2285 DOI: 10.1039/A906391I
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