Issue 4, 2000

Iron(ii)-catalyzed intramolecular aminochlorination of alkenes

Abstract

2-Alkenyloxycarbonyl azides undergo an efficient intramolecular FeII-catalyzed aminochlorination with TMSCl in EtOH and furnish the corresponding 4-(chloromethyl)- oxazolidinones (60–84% yield), presumably via a stepwise single electron transfer pathway.

Article information

Article type
Communication
Submitted
11 Nov 1999
Accepted
20 Dec 1999
First published
03 Feb 2000

Chem. Commun., 2000, 287-288

Iron(II)-catalyzed intramolecular aminochlorination of alkenes

T. Bach, B. Schlummer and K. Harms, Chem. Commun., 2000, 287 DOI: 10.1039/A909009F

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