Issue 11, 2000
From the journal:

Chemical Communications

The structure of the decamethylborocenium cation: the most tightly-squeezed metallocene?

Andreas Voigt,a   Silvia Filipponi,a   Charles L. B. Macdonald,a   John D. Gordena  and  Alan H. Cowley*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas, USA.
E-mail: cowley@mail.utexas.edu

Abstract

X-Ray crystallographic analysis along with DFT calculations on the decamethylborocenium cation provide definitive structural and electronic information about this most tightly-squeezed main group metallocene—the first to adopt the elusive σ/π geometry in the solid state.

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Article information

DOI
https://doi.org/10.1039/B001271H
Article type
Communication
Submitted
09 Feb 2000
Accepted
05 Apr 2000
First published
10 May 2000

Chem. Commun., 2000, 911-912

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The structure of the decamethylborocenium cation: the most tightly-squeezed metallocene?

A. Voigt, S. Filipponi, C. L. B. Macdonald, J. D. Gorden and A. H. Cowley, Chem. Commun., 2000, 911 DOI: 10.1039/B001271H

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